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Q 6.14
Expert-verifiedUse Boltzmann factors to derive the exponential formula for the density of an isothermal atmosphere, already derived in Problems 1.16 and 3.37. (Hint: Let the system be a single air molecule, let s1 be a state with the molecule at sea level, and let s2 be a state with the molecule at height z.)
Therefore, the exponential formula for the density of an isothermal atmosphere is:
Let the system be a single air molecule, let S1 be a state with the molecule at sea level, and let S2 be a state with the molecule at height z.
Consider a system with a single air molecule, where S1 is the state when the molecule is at sea level and S2 is the state when the molecule is at a height of 2. Assume that the energy is only potential energy, so the difference in energy between the states S1 and S2 is the potential energy, which is and the ratio of S2state probability to state s1 probability is:
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This means that the air molecule is less likely to be at height of z than at the see level by a factor of , and that the number of molecules per unit volume at height of z is also smaller than the see level by the same ratio in the isothermal atmosphere, so:
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