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Expert-verifiedIf orbital angular momentum is measured along, say, a z-axis to obtain a value for , show that role="math" localid="1661497092782" is the most that can be said about the other two components of the orbital angular momentum.
It is proved for the other two components of the orbital angular momentum is
.
The orbital angular momentum is measured along a z-axis to get a value .
In quantum mechanics, angular momentum is a vector operator with well-defined commutation relations between its three components.
Using the concept of orbital angular momentum and the value of the momentum in the z-axis in the resultant value of the momentum, define the required expression of the x- and y-component of the angular momentum.
Formulas:
The magnitude of the orbital angular momentum in terms of is,
….. (1)
The z-component of the orbital angular momentum is,
….. (2)
The resultant value of the angular momentum is,
….. (3)
Substituting the values of equations (1) and (2) in equation (3), the required equation to be proved as follows:
For a given value of I, the greatest value of is , so the smallest value of .
Now, the smallest possible value of is zero, thus the largest possible value of is .
So, the range is given by:
Hence, the given equation is proved.
Here are the wavelengths of a few elements:
Element | λ (pm) | Element | λ (pm) |
Ti | 275 | Co | 179 |
V | 250 | Ni | 166 |
Cr | 229 | Cu | 154 |
Mn | 210 | Zn | 143 |
Fe | 193 | Ga | 134 |
Make a Moseley plot (like that in Fig. 40-16) from these data and verify that its slope agrees with the value given for C in Module 40-6.
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