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Modern Physics
Found in: Page 344
Modern Physics

Modern Physics

Book edition 2nd Edition
Author(s) Randy Harris
Pages 633 pages
ISBN 9780805303087

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Short Answer

In its ground state, carbon's 2p electrons interact to produce jT=0. Given Hund's rule. what does this say about the total orbital angular momentum of these electrons?

Total orbital angular momentum is L=2h.

See the step by step solution

Step by Step Solution

Step 1: Total spin of two electrons

The total spin of the two electrons ST is

ST=ST(ST+1)h ….(1)

Step 2: total spin quantum number

The quantum number jT is zero jT=0.

The spin quantum number of each electron is s1=s2=12.

By using Hund's rule, we conclude that the total spin quantum number st is given by

ST=s1+s2=12+12ST=1

Step 3: total spin of electrons

By using Eq. (I), we find the total spin of the electrons sT as

ST=sTsT+1h=1.1+1hST=2h

Step 4: The total orbital angular momentum LT

Now, since jT=0, we conclude that the total orbital angular momentum LT must be equal to the total spin ST

LT=ST=2h

Hence the total orbital angular momentum is LT=2h.

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